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Crystal Structure and Physical Properties of the Cage Compound Hf(2)B(2–2δ)Ir(5+δ)
[Image: see text] Hf(2)B(2–2δ)Ir(5+δ) crystallizes with a new type of structure: space group Pbam, a = 5.6300(3) Å, b = 11.2599(5) Å, and c = 3.8328(2) Å. Nearly 5% of the boron pairs are randomly replaced by single iridium atoms (Ir(5+δ)B(2–2δ)). From an analysis of the chemical bonding, the crysta...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7586331/ https://www.ncbi.nlm.nih.gov/pubmed/32946694 http://dx.doi.org/10.1021/acs.inorgchem.0c02073 |