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A Theoretical Study of the Recently Suggested Mn(VII) Mechanism for O–O Bond Formation in Photosystem II

[Image: see text] The mechanism for water oxidation in photosystem II has been a major topic for several decades. The active catalyst has four manganese atoms connected by bridging oxo bonds, in a complex termed the oxygen-evolving complex (OEC), which also includes a calcium atom. The O–O bond of o...

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Detalles Bibliográficos
Autores principales: Li, Xi-Chen, Li, Jing, Siegbahn, Per E. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7586388/
https://www.ncbi.nlm.nih.gov/pubmed/32877196
http://dx.doi.org/10.1021/acs.jpca.0c05135