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Bis-Phenoxo-Cu(II)(2) Complexes: Formal Aromatic Hydroxylation via Aryl-Cu(III) Intermediate Species

Ullmann-type copper-mediated arylC-O bond formation has attracted the attention of the catalysis and organometallic communities, although the mechanism of these copper-catalyzed coupling reactions remains a subject of debate. We have designed well-defined triazamacrocyclic-based aryl-Cu(III) complex...

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Detalles Bibliográficos
Autores principales: Ribas, Xavi, Xifra, Raül, Fontrodona, Xavier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7587178/
https://www.ncbi.nlm.nih.gov/pubmed/33050208
http://dx.doi.org/10.3390/molecules25204595