Soft Scorpionate Hydridotris(2‐mercapto‐1‐methylimidazolyl) borate) Tungsten‐Oxido and ‐Sulfido Complexes as Acetylene Hydratase Models

A series of W(IV) alkyne complexes with the sulfur‐rich ligand hydridotris(2‐mercapto‐1‐methylimidazolyl) borate) (Tm(Me)) are presented as bio‐inspired models to elucidate the mechanism of the tungstoenzyme acetylene hydratase (AH). The mono‐ and/or bis‐alkyne precursors were reacted with NaTm(Me)...

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Detalles Bibliográficos
Autores principales: Vidovič, Carina, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589279/
https://www.ncbi.nlm.nih.gov/pubmed/32640122
http://dx.doi.org/10.1002/chem.202001127

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589279/
https://www.ncbi.nlm.nih.gov/pubmed/32640122
http://dx.doi.org/10.1002/chem.202001127

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