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Soft Scorpionate Hydridotris(2‐mercapto‐1‐methylimidazolyl) borate) Tungsten‐Oxido and ‐Sulfido Complexes as Acetylene Hydratase Models
A series of W(IV) alkyne complexes with the sulfur‐rich ligand hydridotris(2‐mercapto‐1‐methylimidazolyl) borate) (Tm(Me)) are presented as bio‐inspired models to elucidate the mechanism of the tungstoenzyme acetylene hydratase (AH). The mono‐ and/or bis‐alkyne precursors were reacted with NaTm(Me)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589279/ https://www.ncbi.nlm.nih.gov/pubmed/32640122 http://dx.doi.org/10.1002/chem.202001127 |