Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H(2) Formation

Homogeneous electrocatalytic proton reduction is reported using cobalt complex [1](BF(4))(2). This complex comprises two bis(1‐methyl‐4,5‐diphenyl‐1H‐imidazol‐2‐yl)methane (HBMIM [Formula: see text] ) ligands that contain an acidic methylene moiety in their backbone. Upon reduction of [1](BF(4))(2)...

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Detalles Bibliográficos
Autores principales: Ghosh, Pradip, de Vos, Sander, Lutz, Martin, Gloaguen, Frederic, Schollhammer, Philippe, Moret, Marc‐Etienne, Klein Gebbink, Robertus J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589288/
https://www.ncbi.nlm.nih.gov/pubmed/32350932
http://dx.doi.org/10.1002/chem.201905746

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589288/
https://www.ncbi.nlm.nih.gov/pubmed/32350932
http://dx.doi.org/10.1002/chem.201905746

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