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Atropisomerism in Diarylamines: Structural Requirements and Mechanisms of Conformational Interconversion

In common with other hindered structures containing two aromatic rings linked by a short tether, diarylamines may exhibit atropisomerism (chirality due to restricted rotation). Previous examples have principally been tertiary amines, especially those with cyclic scaffolds. Little is known of the str...

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Detalles Bibliográficos
Autores principales: Costil, Romain, Sterling, Alistair J., Duarte, Fernanda, Clayden, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589358/
https://www.ncbi.nlm.nih.gov/pubmed/32633101
http://dx.doi.org/10.1002/anie.202007595