Regiodivergent C−H and Decarboxylative C−C Alkylation by Ruthenium Catalysis: ortho versus meta Position‐Selectivity

Ruthenium(II)biscarboxylate complexes enabled the selective alkylation of C−H and C−C bonds at the ortho‐ or meta‐position. ortho‐C−H Alkylations were achieved with 4‐, 5‐ as well as 6‐membered halocycloalkanes. Furthermore, the judicious choice of the directing group allowed for a full control of o...

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Detalles Bibliográficos
Autores principales: Korvorapun, Korkit, Moselage, Marc, Struwe, Julia, Rogge, Torben, Messinis, Antonis M., Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589394/
https://www.ncbi.nlm.nih.gov/pubmed/32700444
http://dx.doi.org/10.1002/anie.202007144

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589394/
https://www.ncbi.nlm.nih.gov/pubmed/32700444
http://dx.doi.org/10.1002/anie.202007144

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