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Altering Charges on Heterobimetallic Transition‐Metal Carbonyl Clusters
The homoleptic group 5 carbonylates [M(CO)(6)](−) (M=Nb, Ta) serve as ligands in carbonyl‐terminated heterobimetallic Ag(m)M(n) clusters containing 3 to 11 metal atoms. Based on our serendipitous [Ag(6){Nb(CO)(6)}(4)](2+) (4 a (2+)) precedent, we established access to such Ag(m)M(n) clusters of the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589396/ https://www.ncbi.nlm.nih.gov/pubmed/32613683 http://dx.doi.org/10.1002/chem.202002339 |