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A Redox‐Active Heterobimetallic N‐Heterocyclic Carbene Based on a Bis(imino)pyrazine Ligand Scaffold

A new redox‐active N‐heterocyclic carbene (NHC) architecture is obtained using N‐methylated pyrazinediimine iron complexes as precursors. The new species exhibit strong π‐accepting/σ‐donating properties and are able to ligate two metal centres simultaneously. The redox activity was demonstrated by t...

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Detalles Bibliográficos
Autores principales: Regenauer, Nicolas I., Jänner, Sven, Wadepohl, Hubert, Roşca, Dragoş‐Adrian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590088/
https://www.ncbi.nlm.nih.gov/pubmed/32672368
http://dx.doi.org/10.1002/anie.202005865