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A Redox‐Active Heterobimetallic N‐Heterocyclic Carbene Based on a Bis(imino)pyrazine Ligand Scaffold
A new redox‐active N‐heterocyclic carbene (NHC) architecture is obtained using N‐methylated pyrazinediimine iron complexes as precursors. The new species exhibit strong π‐accepting/σ‐donating properties and are able to ligate two metal centres simultaneously. The redox activity was demonstrated by t...
Autores principales: | Regenauer, Nicolas I., Jänner, Sven, Wadepohl, Hubert, Roşca, Dragoş‐Adrian |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590088/ https://www.ncbi.nlm.nih.gov/pubmed/32672368 http://dx.doi.org/10.1002/anie.202005865 |
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