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Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings

The synthesis, isolation and full characterization of ion pairs between alkaline metal ions (Li(+), Na(+), K(+)) and mono-anions and dianions obtained from 5H-dibenzo[a,d]cycloheptenyl (C(15)H(11) = trop) is reported. According to Nuclear Magnetic Resonance (NMR) spectroscopy, single crystal X-ray a...

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Detalles Bibliográficos
Autores principales: Bloch, Jan, Kradolfer, Stefan, L. Gianetti, Thomas, Ostendorf, Detlev, Dey, Subal, Mougel, Victor, Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7594067/
https://www.ncbi.nlm.nih.gov/pubmed/33076581
http://dx.doi.org/10.3390/molecules25204742