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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
[Image: see text] We report on the synthesis of an alkane-soluble Zintl cluster, [η(4)-Ge(9)(Hyp)(3)]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7596751/ https://www.ncbi.nlm.nih.gov/pubmed/33052653 http://dx.doi.org/10.1021/jacs.0c09742 |