A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

[Image: see text] We report on the synthesis of an alkane-soluble Zintl cluster, [η(4)-Ge(9)(Hyp)(3)]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.

Detalles Bibliográficos
Autores principales: Townrow, Oliver P. E., Chung, Cheuk, Macgregor, Stuart A., Weller, Andrew S., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7596751/
https://www.ncbi.nlm.nih.gov/pubmed/33052653
http://dx.doi.org/10.1021/jacs.0c09742
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author Townrow, Oliver P. E.
Chung, Cheuk
Macgregor, Stuart A.
Weller, Andrew S.
Goicoechea, Jose M.
author_facet Townrow, Oliver P. E.
Chung, Cheuk
Macgregor, Stuart A.
Weller, Andrew S.
Goicoechea, Jose M.
author_sort Townrow, Oliver P. E.
collection PubMed
description [Image: see text] We report on the synthesis of an alkane-soluble Zintl cluster, [η(4)-Ge(9)(Hyp)(3)]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
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spelling pubmed-75967512020-10-30 A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes Townrow, Oliver P. E. Chung, Cheuk Macgregor, Stuart A. Weller, Andrew S. Goicoechea, Jose M. J Am Chem Soc [Image: see text] We report on the synthesis of an alkane-soluble Zintl cluster, [η(4)-Ge(9)(Hyp)(3)]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst. American Chemical Society 2020-10-14 2020-10-28 /pmc/articles/PMC7596751/ /pubmed/33052653 http://dx.doi.org/10.1021/jacs.0c09742 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Townrow, Oliver P. E.
Chung, Cheuk
Macgregor, Stuart A.
Weller, Andrew S.
Goicoechea, Jose M.
A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title_full A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title_fullStr A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title_full_unstemmed A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title_short A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
title_sort neutral heteroatomic zintl cluster for the catalytic hydrogenation of cyclic alkenes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7596751/
https://www.ncbi.nlm.nih.gov/pubmed/33052653
http://dx.doi.org/10.1021/jacs.0c09742
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