A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

[Image: see text] We report on the synthesis of an alkane-soluble Zintl cluster, [η(4)-Ge(9)(Hyp)(3)]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.

Detalles Bibliográficos
Autores principales: Townrow, Oliver P. E., Chung, Cheuk, Macgregor, Stuart A., Weller, Andrew S., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7596751/
https://www.ncbi.nlm.nih.gov/pubmed/33052653
http://dx.doi.org/10.1021/jacs.0c09742

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