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Control of single-ligand chemistry on thiolated Au(25) nanoclusters

Diverse methods have been developed to tailor the number of metal atoms in metal nanoclusters, but control of surface ligand number at a given cluster size is rare. Here we demonstrate that reversible addition and elimination of a single surface thiolate ligand (-SR) on gold nanoclusters can be real...

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Detalles Bibliográficos
Autores principales: Cao, Yitao, Fung, Victor, Yao, Qiaofeng, Chen, Tiankai, Zang, Shuangquan, Jiang, De-en, Xie, Jianping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7603303/
https://www.ncbi.nlm.nih.gov/pubmed/33127904
http://dx.doi.org/10.1038/s41467-020-19327-2