Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides

The first example of enantioselective S−H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95 % ee) and yields (up to 97 %) are achieved for 31 examples in S−H insertion reactions of aryl thiols and α‐carbonyl...

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Detalles Bibliográficos
Autores principales: Momo, Patrícia B., Leveille, Alexandria N., Farrar, Elliot H. E., Grayson, Matthew N., Mattson, Anita E., Burtoloso, Antonio C. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7606806/
https://www.ncbi.nlm.nih.gov/pubmed/32352184
http://dx.doi.org/10.1002/anie.202005563

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7606806/
https://www.ncbi.nlm.nih.gov/pubmed/32352184
http://dx.doi.org/10.1002/anie.202005563

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