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Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides

The first example of enantioselective S−H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95 % ee) and yields (up to 97 %) are achieved for 31 examples in S−H insertion reactions of aryl thiols and α‐carbonyl...

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Detalles Bibliográficos
Autores principales:	Momo, Patrícia B., Leveille, Alexandria N., Farrar, Elliot H. E., Grayson, Matthew N., Mattson, Anita E., Burtoloso, Antonio C. B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7606806/ https://www.ncbi.nlm.nih.gov/pubmed/32352184 http://dx.doi.org/10.1002/anie.202005563

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