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Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes
Chirality typically arises in molecules because of a rigidly chiral arrangement of covalently bonded atoms. Less generally appreciated is that chirality can arise when molecules are threaded through one another to create a mechanical bond. For example, when two macrocycles with chemically distinct f...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7613450/ https://www.ncbi.nlm.nih.gov/pubmed/35760959 http://dx.doi.org/10.1038/s41557-022-00973-6 |