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Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes

Chirality typically arises in molecules because of a rigidly chiral arrangement of covalently bonded atoms. Less generally appreciated is that chirality can arise when molecules are threaded through one another to create a mechanical bond. For example, when two macrocycles with chemically distinct f...

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Detalles Bibliográficos
Autores principales: Maynard, John R.J., Gallagher, Peter, Lozano, David, Butler, Patrick, Goldup, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7613450/
https://www.ncbi.nlm.nih.gov/pubmed/35760959
http://dx.doi.org/10.1038/s41557-022-00973-6