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Enantiodivergent epoxidation of alkenes with a photoswitchable phosphate manganese-salen complex

The development of enantiodivergent catalysts capable of preparing both enantiomeric products from one substrate in a controlled fashion is challenging. Introducing a switching function into the catalyst can address this challenge, allowing the chiral reaction environment to reversibly change during...

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Detalles Bibliográficos
Autores principales: Chen, Xiaofei, Gilissen, Pieter J., Tinnemans, Paul, Vanthuyne, Nicolas, Rutjes, Floris P. J. T., Feringa, Ben L., Elemans, Johannes A.A.W., Nolte, Roeland J.M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7613796/
https://www.ncbi.nlm.nih.gov/pubmed/36353682
http://dx.doi.org/10.1038/s44160-022-00157-7