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Catalytic Enantioselective Alkylation of Indoles with trans-4-Methylthio-β-Nitrostyrene

[Image: see text] The reaction of the rhodium aqua-complex (S(Rh),R(C))-[Cp*Rh{(R)-Prophos} (OH(2))][SbF(6)](2) [Cp* = C(5)Me(5), Prophos = propane-1,2-diyl-bis(diphenylphosphane)] (1) with trans-4-methylthio-β-nitrostyrene (MTNS) gives two linkage isomers (S(Rh),R(C))-[Cp*Rh{(R)-Prophos}(κ(1)O-MTNS...

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Detalles Bibliográficos
Autores principales: Méndez, Isabel, Ferrer, Carlos, Rodríguez, Ricardo, Lahoz, Fernando J., García-Orduña, Pilar, Carmona, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643163/
https://www.ncbi.nlm.nih.gov/pubmed/33163781
http://dx.doi.org/10.1021/acsomega.0c03485