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Crystal structure and spectroscopic properties of aqua­dichlorido­{1,1′-[(pyridine-2,6-diyl-κN)bis(methyl­ene)]bis­(4-butyl-4,5-di­hydro-1H-1,2,4-triazole-5-thione-κN (2))}cobalt(II)

The structure of the title compound, [CoCl(2)(C(19)H(27)N(7)S(2))(H(2)O)], at 173 K has monoclinic (C2/c) symmetry. We report here the synthesis, single-crystal structure, electrospray mass spectrum and NMR spectroscopy of a new six-coordinate cobalt(II) pincer complex. The pincer ligand, in this co...

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Detalles Bibliográficos
Autores principales: Miecznikowski, John R., Jasinski, Jerry P., Ostrowski, Tyler J., Landy, Kendra R., Bonitatibus, Sheila C., Smolinsky, Allison N., Bertolotti, Natalia R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643238/
https://www.ncbi.nlm.nih.gov/pubmed/33209348
http://dx.doi.org/10.1107/S2056989020013547