Zn-Promoted C–H Reductive Elimination and H(2) Activation via a Dual Unsaturated Heterobimetallic Ru–Zn Intermediate

[Image: see text] Reaction of [Ru(PPh(3))(3)HCl] with LiCH(2)TMS, MgMe(2), and ZnMe(2) proceeds with chloride abstraction and alkane elimination to form the bis-cyclometalated derivatives [Ru(PPh(3))(C(6)H(4)PPh(2))(2)H][M′] where [M′] = [Li(THF)(2)](+) (1), [MgMe(THF)(2)](+) (3), and [ZnMe](+) (4),...

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Detalles Bibliográficos
Autores principales: Miloserdov, Fedor M., Rajabi, Nasir A., Lowe, John P., Mahon, Mary F., Macgregor, Stuart A., Whittlesey, Michael K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7660749/
https://www.ncbi.nlm.nih.gov/pubmed/32134645
http://dx.doi.org/10.1021/jacs.0c01062

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7660749/
https://www.ncbi.nlm.nih.gov/pubmed/32134645
http://dx.doi.org/10.1021/jacs.0c01062

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