Polycyclizations of Ketoesters: Synthesis of Complex Tricycles with up to Five Stereogenic Centers from Available Starting Materials

[Image: see text] Here we present a polycyclization of oxotriphenylhexanoates. The polycyclization is governed by electronic effects, and three major synthetic paths have been established leading to stereochemically complex tricyclic frameworks with up to five stereogenic centers. The method is comp...

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Detalles Bibliográficos
Autores principales: Kamlar, Martin, Runemark, August, Císařová, Ivana, Sundén, Henrik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7660947/
https://www.ncbi.nlm.nih.gov/pubmed/33079554
http://dx.doi.org/10.1021/acs.orglett.0c03020

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7660947/
https://www.ncbi.nlm.nih.gov/pubmed/33079554
http://dx.doi.org/10.1021/acs.orglett.0c03020

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