Na(3)FeH(7) and Na(3)CoH(6): Hydrogen-Rich First-Row Transition Metal Hydrides from High Pressure Synthesis

[Image: see text] The formation of ternary hydrogen-rich hydrides involving the first-row transition metals TM = Fe and Co in high oxidation states is demonstrated from in situ synchrotron diffraction studies of reaction mixtures NaH–TM–H(2) at p ≈ 10 GPa. Na(3)FeH(7) and Na(3)CoH(6) feature pentago...

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Detalles Bibliográficos
Autores principales: Spektor, Kristina, Crichton, Wilson A., Filippov, Stanislav, Simak, Sergei I., Fischer, Andreas, Häussermann, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7672699/
https://www.ncbi.nlm.nih.gov/pubmed/33141575
http://dx.doi.org/10.1021/acs.inorgchem.0c02294

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7672699/
https://www.ncbi.nlm.nih.gov/pubmed/33141575
http://dx.doi.org/10.1021/acs.inorgchem.0c02294

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