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Na(3)FeH(7) and Na(3)CoH(6): Hydrogen-Rich First-Row Transition Metal Hydrides from High Pressure Synthesis

[Image: see text] The formation of ternary hydrogen-rich hydrides involving the first-row transition metals TM = Fe and Co in high oxidation states is demonstrated from in situ synchrotron diffraction studies of reaction mixtures NaH–TM–H(2) at p ≈ 10 GPa. Na(3)FeH(7) and Na(3)CoH(6) feature pentago...

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Detalles Bibliográficos
Autores principales:	Spektor, Kristina, Crichton, Wilson A., Filippov, Stanislav, Simak, Sergei I., Fischer, Andreas, Häussermann, Ulrich
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7672699/ https://www.ncbi.nlm.nih.gov/pubmed/33141575 http://dx.doi.org/10.1021/acs.inorgchem.0c02294

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