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Impact of Multiple Hydrogen Bonds with Fluoride on Catalysis: Insight from NMR Spectroscopy

[Image: see text] Hydrogen-bonding interactions have been explored in catalysis, enabling complex chemical reactions. Recently, enantioselective nucleophilic fluorination with metal alkali fluoride has been accomplished with BINAM-derived bisurea catalysts, presenting up to four NH hydrogen-bond don...

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Detalles Bibliográficos
Autores principales: Ibba, Francesco, Pupo, Gabriele, Thompson, Amber L., Brown, John M., Claridge, Timothy D. W., Gouverneur, Véronique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7677927/
https://www.ncbi.nlm.nih.gov/pubmed/33166450
http://dx.doi.org/10.1021/jacs.0c09832