Cargando…

Catalytic Activation of N(2)O at a Low-Valent Bismuth Redox Platform

[Image: see text] Herein we present the catalytic activation of N(2)O at a Bi(I)⇄Bi(III) redox platform. The activation of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts, aided by HBpin as reducing agent. The protocol features remarkably mild conditions (25 °C,...

Descripción completa

Detalles Bibliográficos
Autores principales: Pang, Yue, Leutzsch, Markus, Nöthling, Nils, Cornella, Josep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7677929/
https://www.ncbi.nlm.nih.gov/pubmed/33146996
http://dx.doi.org/10.1021/jacs.0c10092