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Catalytic Activation of N(2)O at a Low-Valent Bismuth Redox Platform
[Image: see text] Herein we present the catalytic activation of N(2)O at a Bi(I)⇄Bi(III) redox platform. The activation of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts, aided by HBpin as reducing agent. The protocol features remarkably mild conditions (25 °C,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7677929/ https://www.ncbi.nlm.nih.gov/pubmed/33146996 http://dx.doi.org/10.1021/jacs.0c10092 |