Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)

[Image: see text] Ylide-substituted phosphines have been shown to be excellent ligands for C–N coupling reactions under mild reaction conditions. Here we report studies on the impact of the steric demand of the substituent in the ylide-backbone on the catalytic activity. Two new YPhos ligands with b...

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Detalles Bibliográficos
Autores principales: Rodstein, Ilja, Prendes, Daniel Sowa, Wickert, Leon, Paaßen, Maurice, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7684579/
https://www.ncbi.nlm.nih.gov/pubmed/32907331
http://dx.doi.org/10.1021/acs.joc.0c01771

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7684579/
https://www.ncbi.nlm.nih.gov/pubmed/32907331
http://dx.doi.org/10.1021/acs.joc.0c01771

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