Cargando…
Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)
[Image: see text] Ylide-substituted phosphines have been shown to be excellent ligands for C–N coupling reactions under mild reaction conditions. Here we report studies on the impact of the steric demand of the substituent in the ylide-backbone on the catalytic activity. Two new YPhos ligands with b...
Autores principales: | Rodstein, Ilja, Prendes, Daniel Sowa, Wickert, Leon, Paaßen, Maurice, Gessner, Viktoria H. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7684579/ https://www.ncbi.nlm.nih.gov/pubmed/32907331 http://dx.doi.org/10.1021/acs.joc.0c01771 |
Ejemplares similares
-
Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature
por: Tappen, Jens, et al.
Publicado: (2020) -
Group 9 and
10 Metal Complexes of an Ylide-Substituted
Phosphine: Coordination versus Cyclometalation and Oxidative Addition
por: Scherpf, Thorsten, et al.
Publicado: (2019) -
Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone:
Angle Dependence of the Donor Strength
por: Löffler, Julian, et al.
Publicado: (2021) -
Unraveling the
High Activity of Ylide-Functionalized
Phosphines in Palladium-Catalyzed Amination Reactions: A Comparative
Study with (Cy)JohnPhos and PtBu(3)
por: Scharf, Lennart T., et al.
Publicado: (2019) -
Coupling of Reformatsky Reagents with Aryl Chlorides Enabled by Ylide‐Functionalized Phosphine Ligands
por: Hu, Zhiyong, et al.
Publicado: (2021)