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An Unusual Skeletal Rearrangement in the Biosynthesis of the Sesquiterpene Trichobrasilenol from Trichoderma

The skeletons of some classes of terpenoids are unusual in that they contain a larger number of Me groups (or their biosynthetic equivalents such as olefinic methylene groups, hydroxymethyl groups, aldehydes, or carboxylic acids and their derivatives) than provided by their oligoprenyl diphosphate p...

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Detalles Bibliográficos
Autores principales: Murai, Keiichi, Lauterbach, Lukas, Teramoto, Kazuya, Quan, Zhiyang, Barra, Lena, Yamamoto, Tsuyoshi, Nonaka, Kenichi, Shiomi, Kazuro, Nishiyama, Makoto, Kuzuyama, Tomohisa, Dickschat, Jeroen S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687074/
https://www.ncbi.nlm.nih.gov/pubmed/31418991
http://dx.doi.org/10.1002/anie.201907964