Formation of Transient Anionic Metal Clusters in Palladium/Diene‐Catalyzed Cross‐Coupling Reactions

Despite their considerable practical value, palladium/1,3‐diene‐catalyzed cross‐coupling reactions between Grignard reagents RMgCl and alkyl halides AlkylX remain mechanistically poorly understood. Herein, we probe the intermediates formed in these reactions by a combination of electrospray‐ionizati...

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Detalles Bibliográficos
Autores principales: Kolter, Marlene, Koszinowski, Konrad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687115/
https://www.ncbi.nlm.nih.gov/pubmed/31335999
http://dx.doi.org/10.1002/chem.201902610

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687115/
https://www.ncbi.nlm.nih.gov/pubmed/31335999
http://dx.doi.org/10.1002/chem.201902610

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