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Persistent Organic High‐Spin Trinitrenes

The septet ground state trinitrenes 1,3,5‐trichloro‐2,4,6‐trinitrenobenzene and 1,3,5‐tribromo‐2,4,6‐trinitrenobenzene were isolated in inert (Ar, Ne, and Xe) as well as reactive matrices (H(2), O(2), and H(2)O) at cryogenic temperatures. These trinitrenes were obtained in high yields by UV photolys...

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Detalles Bibliográficos
Autores principales: Mendez‐Vega, Enrique, Mieres‐Perez, Joel, Chapyshev, Sergei V., Sander, Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687127/
https://www.ncbi.nlm.nih.gov/pubmed/31265166
http://dx.doi.org/10.1002/anie.201904556