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Twisting the TAPPs: Bay‐Substituted Non‐planar Tetraazapero‐pyrenes and their Reduced Anions

A new synthesis of tetraazaperopyrenes (TAPPs) starting from a halogenated perylene derivative 3,4,9,10‐ tetrabromo‐1,6,7,12‐tetrachloroperylene (1) gave access to bay‐substituted TAPPs for the first time. Selective lithiation of the bromine‐positions and subsequent addition of tosyl azide led to th...

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Detalles Bibliográficos
Autores principales: Günther, Benjamin A. R., Höfener, Sebastian, Zschieschang, Ute, Wadepohl, Hubert, Klauk, Hagen, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687186/
https://www.ncbi.nlm.nih.gov/pubmed/31529719
http://dx.doi.org/10.1002/chem.201903413