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Complex Carbocyclic Skeletons from Aryl Ketones through a Three‐Photon Cascade Reaction

Starting from readily available 7‐substituted 1‐indanones, products with a tetracyclo[5.3.1.0(1,7)0(4,11)]undec‐2‐ene skeleton were obtained upon irradiation at λ=350 nm (eight examples, 49–67 % yield). The assembly of the structurally complex carbon framework proceeds in a three‐photon process comp...

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Detalles Bibliográficos
Autores principales: Næsborg, Line, Jandl, Christian, Zech, Andreas, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687228/
https://www.ncbi.nlm.nih.gov/pubmed/31868273
http://dx.doi.org/10.1002/anie.201915731