Cargando…

Complex Carbocyclic Skeletons from Aryl Ketones through a Three‐Photon Cascade Reaction

Starting from readily available 7‐substituted 1‐indanones, products with a tetracyclo[5.3.1.0(1,7)0(4,11)]undec‐2‐ene skeleton were obtained upon irradiation at λ=350 nm (eight examples, 49–67 % yield). The assembly of the structurally complex carbon framework proceeds in a three‐photon process comp...

Descripción completa

Detalles Bibliográficos
Autores principales:	Næsborg, Line, Jandl, Christian, Zech, Andreas, Bach, Thorsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687228/ https://www.ncbi.nlm.nih.gov/pubmed/31868273 http://dx.doi.org/10.1002/anie.201915731

Ejemplares similares

Concise Access to the Skeleton of Protoilludane Sesquiterpenes through a Photochemical Reaction Cascade: Total Synthesis of Atlanticone C
por: Zech, Andreas, et al.
Publicado: (2019)

Concise Total Synthesis of Agarozizanol B via a Strained Photocascade Intermediate
por: Rauscher, Niklas, et al.
Publicado: (2021)

Palladium-Catalyzed Oxidative Domino Carbocyclization–Arylation of Bisallenes
por: Volla, Chandra M. R., et al.
Publicado: (2016)

Efficient Palladium‐Catalyzed Aerobic Arylative Carbocyclization of Enallenynes
por: Liu, Jie, et al.
Publicado: (2018)

Enantioselective Carbocycle Formation through Intramolecular Pd-Catalyzed Allyl–Aryl Cross-Coupling
por: Schuster, Christopher H., et al.
Publicado: (2014)

Alkynyl Prins carbocyclization cascades for the synthesis of linear-fused heterocyclic ring systems
por: Hernandez, Jackson J., et al.
Publicado: (2022)

Chiral Lewis acid catalysis in a visible light-triggered cycloaddition/rearrangement cascade
por: Stegbauer, Simone, et al.
Publicado: (2022)

Sinulariaone A: a novel diterpenoid with a 13-membered carbocyclic skeleton from an octocoral Sinularia species
por: Tseng, Hsuan-Jung, et al.
Publicado: (2023)

Visible Light‐Mediated Dearomative Hydrogen Atom Abstraction/ Cyclization Cascade of Indoles
por: Xiong, Yang, et al.
Publicado: (2022)

Biocatalytic Conversion of Cyclic Ketones Bearing α‐Quaternary Stereocenters into Lactones in an Enantioselective Radical Approach to Medium‐Sized Carbocycles
por: Morrill, Charlotte, et al.
Publicado: (2018)

Highly Efficient Cascade Reaction for Selective Formation of Spirocyclobutenes from Dienallenes via Palladium-Catalyzed Oxidative Double Carbocyclization–Carbonylation–Alkynylation
por: Qiu, Youai, et al.
Publicado: (2016)

One-Pot Three-Component Coupling Reaction of α-Amino Aryl Ketones, Indoles, and Perbromomethane Under Mild Conditions
por: Chen, De, et al.
Publicado: (2022)

Chromium(II)-catalyzed enantioselective arylation of ketones
por: Wang, Gang, et al.
Publicado: (2016)

Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones
por: Ma, Xiaochen, et al.
Publicado: (2017)

Visible Light-Mediated Photochemical Reactions of 2-(2′-Alkenyloxy)cycloalk-2-enones
por: Graßl, Raphaela, et al.
Publicado: (2020)

Different Reaction Patterns in the Baylis-Hillman Reaction of Aryl Aldehydes with Phenyl Vinyl Ketone, Phenyl Acrylate and Phenyl Thioacrylate
por: Shi, Min, et al.
Publicado: (2002)

Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
por: Wang, Xing, et al.
Publicado: (2022)

The first intermolecular interrupted imino-Nazarov reaction: expeditious access to carbocyclic nucleoside analogues
por: William, Ronny, et al.
Publicado: (2016)

Synthesis of Vicinal Carbocycles by Intramolecular Nickel-Catalyzed Conjunctive Cross-Electrophile Coupling Reaction
por: Hewitt, Kirsten A., et al.
Publicado: (2022)

Enantioselective, Visible Light Mediated Aza Paternò–Büchi Reactions of Quinoxalinones
por: Li, Xinyao, et al.
Publicado: (2020)

Arene Activation through Iminium Ions: Product Diversity from Intramolecular Photocycloaddition Reactions
por: Proessdorf, Johanna, et al.
Publicado: (2022)

Synthesis and Biological Evaluation of Carbocyclic Analogues of Pachastrissamine
por: Kwon, Yongseok, et al.
Publicado: (2015)

Palladium-Catalyzed Oxidative Acyloxylation/Carbocyclization of Allenynes**
por: Deng, Youqian, et al.
Publicado: (2013)

9‐Membered Carbocycles: Strategies and Tactics for their Synthesis
por: Huber, Tatjana, et al.
Publicado: (2018)

Synthesis of a Novel Carbocyclic Analog of Bredinin
por: Nair, Vasu, et al.
Publicado: (2013)

Catalytic asymmetric synthesis of carbocyclic C-nucleosides
por: Mishra, Sourabh, et al.
Publicado: (2022)

Three Component Cascade Reaction of Cyclohexanones, Aryl Amines, and Benzoylmethylene Malonates: Cooperative Enamine-Brønsted Acid Approach to Tetrahydroindoles
por: Cortes Vazquez, Jose, et al.
Publicado: (2022)

Reversal of reaction type selectivity by Lewis acid coordination: the ortho photocycloaddition of 1- and 2-naphthaldehyde
por: Stegbauer, Simone, et al.
Publicado: (2019)

Synthesis of (Het)aryl 2-(2-hydroxyaryl)cyclopropyl Ketones
por: Fadeev, Alexander A., et al.
Publicado: (2020)

Computational Analysis of Enantioselective Pd-Catalyzed α-Arylation of Ketones
por: Orlandi, Manuel, et al.
Publicado: (2020)

Aryl Methyl Ketones: Versatile Synthons in the Synthesis of Heterocyclic Compounds
por: Mohammed, Shabber, et al.
Publicado: (2022)

Construction of Eight-Membered Carbocycles with Trisubstituted Double Bonds Using the Ring Closing Metathesis Reaction
por: Tori, Motoo, et al.
Publicado: (2010)

Photocatalyzed Dowd–Beckwith radical-polar crossover reaction for the synthesis of medium-sized carbocyclic compounds
por: Singha, Tushar, et al.
Publicado: (2023)

Synthesis of Dimethyl Aryl Acylsulfonium Bromides from Aryl Methyl Ketones in a DMSO-HBr System
por: Cao, Zhiling, et al.
Publicado: (2013)

Cascade Reaction by Chemo‐ and Biocatalytic Approaches to Obtain Chiral Hydroxy Ketones and anti 1,3‐Diols
por: Gandolfi, Raffaella, et al.
Publicado: (2018)

Palladium‐Catalyzed Oxidative Carbocyclization–Borylation of Enallenes to Cyclobutenes
por: Qiu, Youai, et al.
Publicado: (2016)

Asymmetric Reductive Carbocyclization Using Engineered Ene Reductases
por: Heckenbichler, Kathrin, et al.
Publicado: (2018)

Allylic Carbocyclic Inhibitors Covalently Bind Glycoside Hydrolases
por: Grayfer, Tatyana D., et al.
Publicado: (2023)

Cobalt-assisted route to rare carbocyclic C-ribonucleosides
por: Ojeda-Porras, A. C., et al.
Publicado: (2023)

Catalytic enantioselective radical coupling of activated ketones with N-aryl glycines
por: Liu, Yang, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_9tps9m63oc86bebbnvtupkf8vr