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On the Origin of the Promoting Effect Exerted by Magnesium in the ZnCl(2)-Catalyzed Synthesis of N,N-Diisopropylethylamine

[Image: see text] The reaction of magnesium or zinc amides with alkyl or benzyl halides is an attractive approach to make C–N bonds, especially for electron-poor organic halides. The magnesium-promoted preparation of hindered non-nucleophilic amine (N,N-diisopropylethylamine) from ethyl chloride and...

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Detalles Bibliográficos
Autores principales: Hong, Zeng, Ruan, Jiancheng, Chen, Xinzhi, Qian, Chao, Ge, Xin, Zhou, Shaodong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7689953/
https://www.ncbi.nlm.nih.gov/pubmed/33251426
http://dx.doi.org/10.1021/acsomega.0c04188