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On the Origin of the Promoting Effect Exerted by Magnesium in the ZnCl(2)-Catalyzed Synthesis of N,N-Diisopropylethylamine
[Image: see text] The reaction of magnesium or zinc amides with alkyl or benzyl halides is an attractive approach to make C–N bonds, especially for electron-poor organic halides. The magnesium-promoted preparation of hindered non-nucleophilic amine (N,N-diisopropylethylamine) from ethyl chloride and...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7689953/ https://www.ncbi.nlm.nih.gov/pubmed/33251426 http://dx.doi.org/10.1021/acsomega.0c04188 |