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Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center
Cationic iron complexes [Cp*((i)Pr(2)MeP)FeH(2)SiHR](+), generated and characterized in solution, are very efficient catalysts for the hydrosilation of terminal alkenes and internal alkynes by primary silanes at low catalyst loading (0.1 mol%) and ambient temperature. These reactions yield only the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7690220/ https://www.ncbi.nlm.nih.gov/pubmed/33250975 http://dx.doi.org/10.1039/d0sc01749c |