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Conformationally adaptable macrocyclic receptors for ditopic anions: analysis of chelate cooperativity in aqueous containing media

The effect of chelate cooperativity on the binding of several ditopic anions to two tetrathiourea macrocycles has been analysed in competitive solvent mixtures (H(2)O : DMSO 1 : 9 v/v). The semi-flexible receptors bind dicarboxylates with high affinity dependent on the length and flexibility of the...

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Detalles Bibliográficos
Autores principales: Berry, Stuart N., Qin, Lei, Lewis, William, Jolliffe, Katrina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7690315/
https://www.ncbi.nlm.nih.gov/pubmed/33250974
http://dx.doi.org/10.1039/d0sc02533j