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Photocontrolled Cobalt Catalysis for Selective Hydroboration of α,β‐Unsaturated Ketones

Selectivity between 1,2 and 1,4 addition of a nucleophile to an α,β‐unsaturated carbonyl compound has classically been modified by the addition of stoichiometric additives to the substrate or reagent to increase their “hard” or “soft” character. Here, we demonstrate a conceptually distinct approach...

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Detalles Bibliográficos
Autores principales: Beltran, Frédéric, Bergamaschi, Enrico, Funes‐Ardoiz, Ignacio, Teskey, Christopher J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7692884/
https://www.ncbi.nlm.nih.gov/pubmed/32767728
http://dx.doi.org/10.1002/anie.202009893