A Phosphanyl‐Phosphagallene that Functions as a Frustrated Lewis Pair

Phosphagallenes (1 a/1 b) featuring double bonds between phosphorus and gallium were synthesized by reaction of (phosphanyl)phosphaketenes with the gallium carbenoid Ga(Nacnac) (Nacnac=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)). The stability of these species is dependent on the saturation of the phosphany...

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Detalles Bibliográficos
Autores principales: Wilson, Daniel W. N., Feld, Joey, Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693089/
https://www.ncbi.nlm.nih.gov/pubmed/32615007
http://dx.doi.org/10.1002/anie.202008207

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693089/
https://www.ncbi.nlm.nih.gov/pubmed/32615007
http://dx.doi.org/10.1002/anie.202008207

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