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A Phosphanyl‐Phosphagallene that Functions as a Frustrated Lewis Pair
Phosphagallenes (1 a/1 b) featuring double bonds between phosphorus and gallium were synthesized by reaction of (phosphanyl)phosphaketenes with the gallium carbenoid Ga(Nacnac) (Nacnac=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)). The stability of these species is dependent on the saturation of the phosphany...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693089/ https://www.ncbi.nlm.nih.gov/pubmed/32615007 http://dx.doi.org/10.1002/anie.202008207 |