Cationic NHC‐Phosphine Iridium Complexes: Highly Active Catalysts for Base‐Free Hydrogenation of Ketones

Novel bidentate N‐heterocyclic carbene‐phosphine iridium complexes have been synthesized and evaluated in the hydrogenation of ketones. Reported catalytic systems require base additives and, if excluded, need elevated temperature or high pressure of hydrogen gas to achieve satisfactory reactivity. T...

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Detalles Bibliográficos
Autores principales: Quan, Xu, Kerdphon, Sutthichat, Peters, Bram B. C., Rujirawanich, Janjira, Krajangsri, Suppachai, Jongcharoenkamol, Jira, Andersson, Pher G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693092/
https://www.ncbi.nlm.nih.gov/pubmed/32678969
http://dx.doi.org/10.1002/chem.202002811

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693092/
https://www.ncbi.nlm.nih.gov/pubmed/32678969
http://dx.doi.org/10.1002/chem.202002811

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