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Highly Regioselective Addition of Allylic Zinc Halides and Various Zinc Enolates to [1.1.1]Propellane

We report a range of highly regioselective openings of [1.1.1]propellane with various allylic zinc halides, as well as zinc enolates of ketones, esters and nitriles. The resulting zincated bicyclopentanes (BCPs) were trapped with a range of electrophiles including acyl chlorides, sulfonothioates, hy...

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Detalles Bibliográficos
Autores principales: Schwärzer, Kuno, Zipse, Hendrik, Karaghiosoff, Konstantin, Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693202/
https://www.ncbi.nlm.nih.gov/pubmed/32744419
http://dx.doi.org/10.1002/anie.202009340