Arene C−H Activation at Aluminium(I): meta Selectivity Driven by the Electronics of S(N)Ar Chemistry

The reactivity of the electron‐rich anionic Al(I) aluminyl compound K(2)[(NON)Al](2) (NON=4,5‐bis(2,6‐diisopropylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene) towards mono‐ and disubstituted arenes is reported. C−H activation chemistry with n‐butylbenzene gives exclusively the product of activati...

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Detalles Bibliográficos
Autores principales: Hicks, Jamie, Vasko, Petra, Heilmann, Andreas, Goicoechea, Jose M., Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693242/
https://www.ncbi.nlm.nih.gov/pubmed/32722863
http://dx.doi.org/10.1002/anie.202008557

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693242/
https://www.ncbi.nlm.nih.gov/pubmed/32722863
http://dx.doi.org/10.1002/anie.202008557

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