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Comparative Studies on Regioselectivity of α- and β-Linked Glucan Tosylation

Alpha- and beta-linked 1,3-glucans have been subjected to conversion with p-toluenesulfonic acid (tosyl) chloride and triethylamine under homogeneous reaction conditions in N,N-dimethyl acetamide/LiCl. Samples with a degree of substitution of tosyl groups (DS(Ts)) of up to 1.91 were prepared by appl...

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Detalles Bibliográficos
Autores principales: Koschella, Andreas, Heinze, Thomas, Tied, Antje, Geitel, Katja, Chien, Chih-Ying, Iwata, Tadahisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698535/
https://www.ncbi.nlm.nih.gov/pubmed/33213089
http://dx.doi.org/10.3390/molecules25225382