Linkage Isomerism Leading to Contrasting Carboboration Chemistry: Access to Three Constitutional Isomers of a Borylated Phosphaalkene

We describe the reactivity of two linkage isomers of a boryl‐phosphaethynolate, [B]OCP and [B]PCO (where [B]=N,N’‐bis(2,6‐diisopropylphenyl)‐2,3‐dihydro‐1H‐1,3,2‐diazaboryl), towards tris‐ (pentafluorophenyl)borane (BCF). These reactions afforded three constitutional isomers all of which contain a p...

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Detalles Bibliográficos
Autores principales: Wilson, Daniel W. N., Mehta, Meera, Franco, Mauricio P., McGrady, John E., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702093/
https://www.ncbi.nlm.nih.gov/pubmed/32495945
http://dx.doi.org/10.1002/chem.202002226

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702093/
https://www.ncbi.nlm.nih.gov/pubmed/32495945
http://dx.doi.org/10.1002/chem.202002226

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