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Linkage Isomerism Leading to Contrasting Carboboration Chemistry: Access to Three Constitutional Isomers of a Borylated Phosphaalkene
We describe the reactivity of two linkage isomers of a boryl‐phosphaethynolate, [B]OCP and [B]PCO (where [B]=N,N’‐bis(2,6‐diisopropylphenyl)‐2,3‐dihydro‐1H‐1,3,2‐diazaboryl), towards tris‐ (pentafluorophenyl)borane (BCF). These reactions afforded three constitutional isomers all of which contain a p...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702093/ https://www.ncbi.nlm.nih.gov/pubmed/32495945 http://dx.doi.org/10.1002/chem.202002226 |