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Effect of Larger Pore Size on the Sorption Properties of Isoreticular Metal–Organic Frameworks with High Number of Open Metal Sites

Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydroxynaphthalene‐2,6‐dicarboxylic acid and divalent cations (M=Mn, Mg, Ni, Co) are shown to be isoreticular to the CPO‐27 (MOF‐74) materials. Desolvated CPO‐54‐Mn contains a very high concentration of ope...

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Detalles Bibliográficos
Autores principales: Dietzel, Pascal D. C., Georgiev, Peter A., Frøseth, Morten, Johnsen, Rune E., Fjellvåg, Helmer, Blom, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702128/
https://www.ncbi.nlm.nih.gov/pubmed/32428361
http://dx.doi.org/10.1002/chem.202001825